以铜铝合金粉为原料,利用反应球磨并结合放电等离子烧结工艺制备了Al2O3/Cu复合材料,研究了球磨不同时间后合金粉的形貌、物相以及铝含量对复合材料组织与性能的影响。结果表明:铜铝合金粉球磨20 h后,生成了粒径为2~5 μm的类球状颗粒,Cu相衍射峰发生明显的宽化,在铜基体中原位生成了纳米α-Al2O3颗粒相;Al2O3颗粒的尺寸及其在基体中的分布与铝含量有关,随着铝含量增加,Al2O3颗粒逐渐长大、富集甚至团聚;复合材料的相对密度和导电率均随着铝含量的增加逐渐降低,显微硬度则逐渐升高;当铝的质量分数为0.7%时,复合材料具有最佳的综合性能。
所属栏目
新材料新工艺重点实验室基金资助项目(9140C850201110C85);“十二五”装备预先研究项目(51326020202)
收稿日期
2013/11/12014/8/29
作者单位
刘贵民:装甲兵工程学院装备再制造工程系, 北京 100072
李斌:装甲兵工程学院装备再制造工程系, 北京 100072
闫涛:装甲兵工程学院装备再制造工程系, 北京 100072
郑晓辉:装甲兵工程学院装备再制造工程系, 北京 100072
丁华东:装甲兵工程学院装备再制造工程系, 北京 100072
备注
刘贵民(1971-),男,山东阳谷人,教授,博士。
引用该论文:
LIU Gui-min,LI Bin,YAN Tao,ZHENG Xiao-hui,DING Hua-dong.Microstructure and Properties of Al2O3/Cu Composite Prepared by Reaction Milling Following Sintering[J].Materials for mechancial engineering,2015,39(1):63~67
刘贵民,李斌,闫涛,郑晓辉,丁华东.反应球磨烧结制备Al2O3/Cu复合材料的组织与性能[J].机械工程材料,2015,39(1):63~67
被引情况:
【1】
王天国,覃群, "烧结温度对铜基粉末冶金摩擦材料组织和性能的影响",机械工程材料
40, 39-42(2016)
参考文献
【1】
SURYANARAYANA C,NASSER A A. Mechanically alloyed nanocomposites[J].Progress in Materials Science,2013,58:383-502.
【2】
郭明星,汪明朴,李周,等.原位复合法制备纳米粒子弥散强化铜合金研究进展[J].机械工程材料,2005,29(4):1-3.
【3】
ZHANG D L,RICHMOND J J. Microstructural evolution during combustion reaction between CuO and Al induced by high energy ball milling[J].Journal of Materials Science,1999,34:701-706.
【4】
VENUGOPAL T,PRASAD R K,MURTY B S. Synthesis of copper-alumina nanocomposite by reactive milling[J].Materials Science and Engineering:A,2005,393:382-386.
【5】
YING D Y,ZHANG D L. Processing of Cu-Al2O3 metal matrix nanocomposite materials by using high energy ball milling[J].Materials Science and Engineering:A,2000,286:152-156.
【6】
RAJKOVIC V,BOZIC D,JOVANOVIC M T. Properties of copper matrix reinforced with various size and amount of Al2O3 particales[J].Journal of Materials Processing Technology,2008,200:106-114.
【7】
RAJKOVIC V,BOZIC D,JOVANOVIC M T. Effects of copper and Al2O3 particles on characteristics of Cu-Al2O3 composites[J].Materials and Design,2010,31:1962-1970.
【8】
RAJKOVIC V,BOZIC D,DEVECERSKI A. Characteristic of copper matrix simultaneously reinforced with nano-and micro-sized Al2O3 particles[J].Materials Characterization,2012,67:129-137.
【9】
VENCL A,RAJKVOIC V,ZIVIC F,et al. The effect of processing techniques on microstructural and tribological properties of copper-based alloys[J].Applied Surface Science,2013,280:646-654.
【10】
YAN Peng,LIN Chen-guang,CUI Shun,et al. Microstructural features properties of high-hardness and heat-resistant dispersion strengthened copper by reaction milling[J].Journal of Wuhan University of Technology-Mater Sci Ed,2011,26(5):902-907.
【11】
LIANG Shu-hua,WANG Xian-hui,KONG De-ming,et al. Preparation of Cu/Cr2O3 composites by mechanical activation and in situ oxidation[J].Journal of Composite Materials,2010,44(9):1049-1060.
【12】
田宝红,宋克兴,刘平,等.高性能弥散强化铜基复合材料及其制备技术[M].北京:科学出版社,2012:6.
【13】
TJONG S C. Novel nanoparticle-reinforced metal matrix composites with enhanced mechanical properties[J].Advanced Engineering Materials,2007,8:639-652.