综述了粉体尺寸、烧结温度、保温时间、掺杂剂的选择及含量等对TiO
2压敏陶瓷压敏电压、非线性系数、介电损耗和介电常数等电性能以及晶体微观结构影响的研究现状,并指出TiO
2压敏陶瓷在小型化和多功能化等方面的发展是今后重要的研究方向。
所属栏目
综述上海市优秀技术带头人计划资助项目(14XD1425400)
收稿日期
2015/10/272016/11/29
作者单位
王宇:上海工程技术大学材料工程学院, 上海 201620
张可敏:上海工程技术大学材料工程学院, 上海 201620
李文戈:上海海事大学商船学院, 上海 201306
尧巍华:东莞易力禾有限公司, 东莞 523750
备注
王宇(1992-),男,江苏扬州人,硕士研究生。
引用该论文:
WANG Yu,ZHANG Ke-min,LI Wen-ge,YAO Wei-hua.Research Status of TiO2 Based Varistor Ceramics[J].Materials for mechancial engineering,2017,41(1):1~6
王宇,张可敏,李文戈,尧巍华.TiO2压敏陶瓷电性能的研究现状[J].机械工程材料,2017,41(1):1~6
参考文献
【1】
袁明军, 崔文权, 李苹,等. TiO2压敏电阻的研究与应用[J]. 材料科学与工艺, 2008(6):751-754.
【2】
SANTANA M A A, SANTORS F S N D, SOUSA V C,et al. Variability sources of DC voltage-current measurements in the study of TiO2-based varistors[J]. Measurement, 2008, 41(10):1105-1112.
【3】
FU Q, CHEN T, YE X,et al. ZnO varistor ceramics prepared by the reduction-reoxidation method[J]. Journal of the European Ceramic Society, 2015, 35(11):3025-3031.
【4】
海参威, 李文戈, 尧巍华,等. 表面活性剂SPAN80对水热法制备SrTiO3粉体物相、形貌与极性的影响[J]. 机械工程材料, 2014, 38(12):65-68.
【5】
WANG N Z, LI J Y, NING J,et al. Effect of Mn, Si on varistor-dielectric characteristics of Nb-doped SrTiO3 ceramics[J]. Applied Mechanics & Materials, 2012, 239/240:1604-1608.
【6】
ZOU M, WANG Y, CHEN Y Y,et al. Influences of donor additives on properties of TiO2-based varistor[J]. Advanced Materials Research, 2010, 105/106:320-323.
【7】
KANG K Y, GAN G Y, YAN J K,et al. Effect of Ge-GeO2 Co-doping on non-ohmic behaviour of TiO2-V2O5-Y2O3 varistor ceramics[J]. Journal of Semiconductors, 2015, 36(7):073005.
【8】
SOUSA V C, OLIVERIRA M M, ORLANDI M O,et al. Microstructure and electrical properties of (Ta, Co, Pr) doped TiO2 based electroceramics[J]. Journal of Materials Science Materials in Electronics, 2010, 21(3):246-251.
【9】
梁忠. V5+、Y3+掺杂TiO2压敏陶瓷的制备及性能研究[D]. 昆明:昆明理工大学, 2014.
【10】
WANG T G, QIN Q, ZHANG W J. Effect of TiO2 nano powder on the microstructure and electrical properties of TiO2 capacitor-varistor ceramics[J]. Advanced Materials Research, 2011, 341/342:94-97.
【11】
LIN C, FAN Z W, XU Z,et al. Influence of different nano titania on microstructure and electrical properties of low voltage zinc oxide varistors[J].Journal of Electroceramics,2008, 21:423-426.
【12】
BADEV A, MARINEL S, HEUGUET R, et al. Sintering behavior and non-linear properties of ZnO varistors processed in microwave electric and magnetic fields at 2.45 GHz[J]. Acta Materialia, 2013, 61(20):7849-7858.
【13】
ZHAO J, WANG B, LU K. Influence of Ta2O5 doping and microwave sintering on TiO2-based varistor properties[J]. Ceramics International, 2014, 40(9):14229-14234.
【14】
KHARCHOUCHE F, SAVARY E, THUAULT A,et al. Effects of microwave sintering on intrinsic defects concentrations in ZnO-based varistors[J]. Ceramics International, 2014, 40(8):13697-13701.
【15】
CONG L, BO W, ZHENG X,et al. Densification and electrical properties of zinc oxide varistors microwave-sintered under different oxygen partial pressures[J]. Journal of Electronic Materials, 2012, 41(11):3119-3124.
【16】
LIN C. Densification and grain growth of microwave sintered ZnO varistors[J]. Journal of Inorganic Materials, 2007, 22(5):917-921.
【17】
孙质彬, 王昕, 尹衍升,等. 叠层方式烧结对TiO2环形压敏电阻电性能的影响[J]. 机械工程材料, 2013, 37(2):86-89.
【18】
NAGAOKA K, JENTYS A, LERCHER J A. Methane autothermal reforming with and without ethane over mono- and bimetal catalysts prepared from hydrotalcite precursors[J]. Journal of Catalysis, 2005, 229(1):185-196.
【19】
严继康, 甘国友, 陈海芳,等. 烧结温度对TiO2压敏陶瓷结构和性能的影响[J]. 压电与声光, 2008, 37(3):332-334.
【20】
WANG T G, QIN Q, ZHANG W J. Effect of temperature on microstructure and electrical properties of (Y, Ta)-doped TiO2 capacitor-varistor ceramics[J].Advanced Materials Research,2011,214:173-177.
【21】
CHEN Y Y, ZOU M, WANG Y,et al. Influences of sintering temperature on microstructure and electrical properties of TiO2 varistor ceramics[J].Advanced Materials Research,2010,105/106:317-319.
【22】
MENG F M, AUN Z Q. Influence of soaking time on semi-conductivity and nonlinear electrical properties of TiO2-based varistor ceramics[J]. Journal of Chongqing University(English Edition), 2008,7(4):297-301.
【23】
王晓青. TiO2基低压压敏陶瓷材料的制备与性能研究[D]. 广州:华南理工大学, 2012.
【24】
FOLLADOR N R, SOUZA E, ANDRADE A,et al. Influence of Nb2O5 on the varistor behavior of TiO2-Cr2O3 system[J]. Journal of Materials Science Materials in Electronics, 2013, 24(3):938-944.
【25】
SOUSA V C D, OLICEIRA M M, ORLANDI M,et al. (Ta, Cr)-doped TiO2 electroceramic systems[J]. Journal of Materials Science Materials in Electronics, 2006, 17(1):79-84.
【26】
SOUSA V C, OLICEIRA M M, ORLANDI M O,et al. Microstructure and electrical properties of (Ta, Co, Pr)-doped TiO2 based electroceramics[J]. Journal of Materials Science Materials in Electronics, 2010, 21(3):246-251.
【27】
LUO S, TANG Z, LI J, et al. Effect of Ta2O5 in (Ca, Si, Ta)-doped TiO2ceramic varistors[J]. Ceramics International, 2008, 34(5):1345-1347.
【28】
GONG Y, CHU R, XU Z,et al. Electrical properties of Ta2O5-doped TiO2 varistor ceramics sintered at low-temperature[J]. Ceramics International, 2015, 41(7):9183-9187.
【29】
SHANNON R D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides[J]. Acta Crystallographica, 1976, 32(5):751-767.
【30】
朱道云, 周方桥, 丁志文,等. Nb2O5掺杂及TiO2压敏陶瓷埋烧工艺的研究[J]. 华中科技大学学报(自然科学版), 2004(2):54-57.
【31】
孟凡明, 傅刚, 胡素梅,等. Ta2O5与Nb2O5对TiO2基压敏陶瓷电性能的影响[J].硅酸盐学报, 2004(12):1496-1499.
【32】
DELBRVCKE T, SCHMIDT I, CAVA S,et al. Electrical properties of a TiO2-SrO varistor system[J]. Advanced Materials Research, 2014, 975:168-172.
【33】
WANG Q, LIAN G, DCIKEY E C. Grain boundary segregation in yttrium-doped polycrystalline TiO2[J]. Acta Materialia, 2004, 52(4):809-820.
【34】
YAN J, GAN G, DU J,et al. Second phases of (La,Nb)-Codoped TiO2 varistor ceramic[C]//Journal of Physics Conference Series Journal of Physics Conference Series.[S.l.]:[s.n.], 2009.
【35】
BOMIO M R D, SOUSA V C, LEITO E R,et al. Nonlinear behavior of TiO2·Ta2O5·MnO2 material doped with BaO and Bi2O3[J]. Materials Chemistry & Physics, 2004, 85(1):96-103.
【36】
李莉, 屈晓田. Bi2O3对TiO2系压敏陶瓷性能的影响[J]. 电子元件与材料, 2007(3):49-51.
【37】
PENG Z J, RUICHAO G, FENG J,et al. Microstructure and nonohmic properties of SnO2-Ta2O5-TiO2 varistor system doped with CuO[J]. International Journal of Modern Physics B, 2014, 28(15):817-824.