概述了含氟聚合物低表面能防污涂层的发展现状,重点介绍了新型含氟低表面能防污涂层中氟碳功能基团存在于主干和支链上的性能特点,归纳了制备工艺、分子链结构、相对分子质量、微观结构以及接枝PEG等对聚合物涂层表面性能的影响,最后总结了含氟低表面能防污涂层存在的问题,并对防污涂层研究的前景进行了展望.
所属栏目
综述海南大学地方服务项目(HDSF201308);上海市科技人才计划项目(12XD1421300)
收稿日期
2013/12/62014/9/10
作者单位
李江:海南大学,海南省特种玻璃实验室, 海口 570228
汪国庆:海南大学,海南省特种玻璃实验室, 海口 570228上海暄洋化工材料科技有限公司, 上海 201611
丁春华:海南大学,海南省特种玻璃实验室, 海口 570228
姜宏:海南大学,海南省特种玻璃实验室, 海口 570228
备注
李江(1989-),男,湖北黄冈人,硕士研究生.
引用该论文:
LI Jiang,WANG Guo-qing,DING Chun-hua,JIANG Hong.Research Progress of Novel Fluorinated Polymer Low Surface Energy Antifouling Coatings[J].Materials for mechancial engineering,2015,39(3):1～6
李江,汪国庆,丁春华,姜宏.新型含氟聚合物低表面能防污涂层的研究进展[J].机械工程材料,2015,39(3):1～6
参考文献
【1】
BERNTSSON K M,JONSSON P R,LEJHALL M,et al.Analysis of behavioural rejection of micro-textured surfaces and implications for recruitment by the barnacle Balanus improvisus[J].J Exp Mar Biol Ecol,2000,251:59-83.
【2】
GUDIPATI C S,FINLAY J A,CALLOW J A,et al.The antifouling and fouling-release perfomance of hyperbranched fluoropolymer(HBFP)-poly(ethylene glycol)(PEG) composite coatings evaluated by adsorption of biomacromolecules and the green fouling alga Ulva[J].Langmuir,2005,21:3044-3053.
【3】
OLSE S M,PEDERSEN L T,LAURSEN M H,et al.Enzyme-based antifouling coatings:a review[J].Biofouling,2007,23:369-383.
【4】
P REZ-ROA R E,ANDERSON M A,RITTSCHOF D,et al.Inhibition of barnacle(amphibalanus amphitrite) cyprid settlement by means of localized,pulsed electric fields[J].Biofouling,2008,24:177-184.
【5】
EKBLAD T,BERGSTRM G,EDERTH T,et al.Triblock copolymers with grafted fluorine-free,amphiphilic,non-ionic side chains for antifouling and fouling-release applications[J].Biomacromolecules,2008,9:2775-2783.
【6】
ANDERSON C D,ATLAR M,CALLOW M E,et al.The development of foul-release coatings for sea going vessels[J].J Mar Des Oper,2003,4:11-23.
【7】
Robbart E.Ship's hull coated with anti-fouling silicone resin and method of coating:US,2986474[P].1961-05-30.
【8】
ANDERSON C D,ATLAR M,CALLOW M E,et al.The development of foul-release coatings for sea going vessels[J].J Mar Des Oper,2003,4:11-23.
【9】
边蕴静.低表面能防污涂料的防污特性理论分析[J].中国涂料,2000(5):36-39.
【10】
WANG Y P,BETTS D E,FINLAY J A,et al.Photocurable amphiphilic perfluoropolyether/poly(ethylene glycol) networks for fouling-release coatings[J].Macromolecules,2011,44:878-885.
【11】
BRADY R F,SINGER L L.Mechanical factors favoring release from fouling release coatings[J].Biofouling,2000,15:73-81.
【12】
YARBROUGH J C,ROLLAND J P,DESIMONE J M,et al.Contact angle analysis,surface dynamics,and biofouling characteristics of cross-linkable,random perfluoropolyether-based graft terpolymers[J].Macromolecules,2006,39:2521-2528.
【13】
PITTMAN A G.In fluoropolymers[M].New York:Wiley,1972.
【14】
BRADY R F J,GRIGGITH J R,LOVE K S,et al.Non-toxic alternatives to antifouling paints[J].Journal of Coatings for Technol,1987,59:113-119.
【15】
杨继年,丁国新,王周锋,等.非生物降解热塑性弹性体在增韧聚乳酸中的应用[J].机械工程材料,2014,38(5):1-5.
【16】
SHULL K R,KRAMER E J,HADZIIOANNOU G,et al.Segregation of block copolymers to interfaces between immiscible homopolymers[J].Macromolecules,1990,23:4780-4787.
【17】
TUMINELLO W H,GREGORY T D.Thermodynamies of poly(tetrafluoroethylene) solubility[J].Macromolecules,1994,27:669-676.
【18】
SCHEIRS J.Modern fluoropolymers[M].New York:Wiley,1997.
【19】
BARTOSZEK E J,PERILLON J L.Long life coatings with PVDF polymers[J].Surface Coatings International,1995,9:371-376.
【20】
YOON S C,RATNER B D.Surface and bulk structure of segmented poly(ether urethanes) with perfluoro chain extenders-part 3:effcets of annealing,casting solvent,and casting conditions[J].Macromolecules,1988,21:2401-2404.
【21】
KRUPERS M,SLANGEN P J,MOLLER M.Synthesis and properties of polymers based on oligo(hexafluoropropene oxide) containing methaerylates and copolymers with methyl methacrylate[J].Macromolecules,1998,31:2552-2558.
【22】
KOBERSTEIN J T.Molecular design of functional polymer surfaces[J].J Polym Sci:B,2004,42:2942-2956.
【23】
HIRAO A,KOIDE G,SUGIYAMA K.Synthesis of novel well-defined chain-end-and in chain functionalized polystyrenes with one,two,three,and four perfluorooctyl groups and their surface characterization[J].Macromolecules,2002,35:7642-7651.
【24】
EI-SHEHAWY A A,YOKOYAMA H,SUGIYAMA K,et al.Precise synthesis of novel chain-end-functionalized polystyrenes with a definite number of perfluorooctyl groups and their surface characterization[J].Maeromoleeules,2005,38:8285-8299.
【25】
MUISENER P R,KOBERSTEIN J T,KUMAR S.Optimal chain architectures for the molecular design of functional polymer surfaces[J].Maeromolecules,2003,36:771-781.
【26】
TANAKA K,KAWAGUCHI D,YOKOE Y,et al.Surface segregation of chain ends in α,ω-fluoroalkyl-terminated polystyrenes films[J].Polymer,2003,44:4171-4177.
【27】
武兵,李欣欣,焦健,等.原子转移自由基聚合制备含氟嵌段共聚物及其性能[J].华东理工大学学报,2001,27(1):60-63.
【28】
李晓艳,仇伟,李欣欣,等.带有羧基的含氟丙烯酸酯共聚物的制备及超疏水性能研究[J].化学学报,2011,69(12):1425-1430.
【29】
陈建兵,王武生,王宇,等.聚含氟丙烯酸酯聚氨酯三嵌段共聚物水基分散体的合成及膜结构[J].应用化学,2006,23(2):198-202.
【30】
QIN Shan,LI Hong,YUAN Wang-zhang,et al.Fluorine-containing block copolymer particles with surface and internal hierarchical microphase separation structures[J].Soft Matter,2012,8:2471-2476.
【31】
WANG Jian-guo,MAO Guo-ping,OBER C K,et al.Liquid crystalline,semifluorinated side group block copolymers with stable low energy surfaces:synthesis,liquid crystalline structure,and critical surface tension[J].Macromolecules,1997,30:1906-1914.
【32】
CHO Y,SUNDARAM H S,WEINMAN C J,et al.Triblock copolymers with grafted fluorine-free,amphiphilic,non-ionic side chains for antifouling and fouling-release applications[J].Macromolecules,2011,44:4783-4792.
【33】
KANG S,ASATEKIN A,MAYES A M,et al.Protein antifouling mechanisms of PAN UF membranes incorporating PAN-g-PEO additive[J].J Membr Sci,2007,296:42-50.
【34】
KIM D G,KANG H,HAN S,et al.Dual effective organic/inorganic hybrid star-shaped polymer coatings on ultrafiltration membrane for bio- and oil-fouling resistance[J].Appl Mater Interfaces,2012,4:5898-5906.
【35】
KRISHNAN S,WANG N,OBER C K,et al.Comparison of the fouling release properties of hydrophobic fluorinated and hydrophilic pegylated block copolymer surfaces:attachment strength of the diatom navicula and the green alga ulva[J].Biomacromolecules,2006,7:1449-1462.
【36】
SUNDARAM H S,CHO Y,DIMITRIOU M D,et al.Fluorinated amphiphilic polymers and their blends for fouling-release applications:the benefits of a triblock copolymer surface[J].Appl Mater Interfaces,2011,3:3366-3374.
【37】
WEINMAN C J,FINLAY J A,PARK D,et al.ABC triblock surface active block copolymer with grafted ethoxylated fluoroalkyl amphiphilic side chains for marine antifouling/fouling-release applications[J].Langmuir,2009,25:12266-12274.
