以Hummers法制备的氧化石墨烯和管径为30~50 nm、长50~100
μm的碳纳米管为原料,采用水热还原法及冷冻干燥处理制备了石墨烯气凝胶和石墨烯/碳纳米管气凝胶,研究了气凝胶的物相组成、微观形貌和弹性性能,分析了碳纳米管对弹性性能的影响机理。结果表明:两种气凝胶均具有三维多孔结构,碳纳米管均匀地分布在石墨烯上,并且缠绕在石墨烯片层的内壁和片层间的连接点处;石墨烯/碳纳米管气凝胶的可回复压缩变形量高达90%,远大于石墨烯气凝胶的;碳纳米管可以有效地防止层叠石墨烯片层间的滑动,提高石墨烯的结构稳固性。
所属栏目
新材料 新工艺江苏省自然科学基金资助项目(BK20140869);南京邮电大学引进人才基金资助项目(NY213082)
收稿日期
2015/7/312016/11/18
作者单位
刁煜:南京邮电大学光电工程学院, 南京 210023
汤厚睿:南京邮电大学光电工程学院, 南京 210023
吕鹏:南京邮电大学光电工程学院, 南京 210023
备注
刁煜(1993-),女,江苏淮安人,本科生。
引用该论文:
DIAO Yu,TANG Hou-rui,LÜ,Peng.Preparation and Elasticity Property of Graphene/Carbon Nanotube Aerogel[J].Materials for mechancial engineering,2017,41(2):72~76
刁煜,汤厚睿,吕鹏.石墨烯/碳纳米管气凝胶的制备及其弹性性能[J].机械工程材料,2017,41(2):72~76
参考文献
【1】
付猛,张婷婷,龚利云,等. 化学分散法制备少数层石墨烯及其表征[J]. 机械工程材料,2011,35(12):89-93.
【2】
康怡然,蔡锋,陈宏源,等. 碳纳米管/石墨烯复合结构及其电化学[J]. 化学进展,2014,26(9):1562-1569.
【3】
WANG Y,HUANG Y,SONG Y,et al. Room temperature ferromagnetism of graphene[J]. Nano Lett,2009,9(1):220-224.
【4】
BERGER C, SONG Z, LI T, et al. Ultrathin epitaxial graphite:2D electron gas properties and a route toward graphene-based nanoelectronics[J]. The Journal of Physical Chemistry B, 2004, 108(52):19912-19916.
【5】
DI C A,WEI D C,YU G,et al. Patterned graphene as source/drain electrodes for bottom-contact organic filed-effect transistors[J]. Advanced Materials, 2008, 20(17):3289-3293.
【6】
WU J S,PISULA W,MULLEN K. Graphenes as potential material for electronics[J]. Chemical Reviews, 2007, 107(3):718-747.
【7】
STANKOVICH S,PINER R D,NGUYEN S T,et al. Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets[J]. Carbon,2006,44(15):3342-3347.
【8】
XIE X,YU G,LIU N,et al. Graphene sponges as high-performance low-cost anodes for anodes for microbial fuel cells[J]. Energy & Environment Science,2012,5(5):6862-6866.
【9】
XU C,CUI A J,XU Y L,et al. Graphene oxide-TiO2 composite filtration membranes and their potential application for water purification[J]. Carbon,2013,62(6):465-471.
【10】
ZENG L J,WANG R,ZHU L H,et al. Graphene and CdS nanocomposite:A facile interface for construction of DNA-based electrochemical biosensor and its application to the determination of phenformin[J]. Colloids and Surfaces B:Biointerfaces,2013,110:8-14.
【11】
QIU L, LIU J Z, CHANG S L Y,et al. Biomimetic superelastic graphene-based cellular monoliths[J/OL]. Nature Communications, 2012, 3:1241.
【12】
LI Y R, CHEN J, HUANG L,et al. Highly compressible macroporous graphene monoliths via an improved hydrothermal process[J]. Advanced Materials, 2014, 26(28):4789-4793.
【13】
辜萍,王宇,李广海. 碳纳米管的力学性能及碳纳米管复合材料研究[J]. 力学进展,2012,32(4):563-573.
【14】
HUMMERS Jr W S, OFFEMAN R E. Preparation of graphitic oxide[J]. Journal of the American Chemical Society, 1958, 80(6):1339-1339.
【15】
SUN H Y, XU Z, GAO C. Multifunctional, ultra-flyweight, synergistically assembled carbon aerogels[J]. Advanced Materials, 2013, 25(18):2554-2560.
【16】
ZHONG J, MENG J, GUI X C,et al. Nanocarbon aerogel complexes inspired by the leaf structure[J]. Carbon, 2014, 77:637-644.