绿色环保的聚丙烯(PP)泡沫材料具有优异的物化、力学性能和易再生、易分解等环境友好特性, 其研发受到国内外的广泛关注。主要综述了近十年来用于制备PP泡沫材料的发泡成型工艺发展情况, 以及PP发泡效果和物理、力学性能的影响因素, 并对该领域今后的研究方向进行了展望。

所属栏目

综述江苏省自然科学基金资助项目(BK2009379); 安徽理工大学青年教师科学研究基金资助项目

收稿日期

2011/7/202012/3/21

作者单位

杨继年:安徽理工大学材料科学与工程学院, 淮南 232001
许爱琴:北京美盛沃利工程技术有限公司南京分公司, 南京 210019

备注

杨继年(1981-), 男, 江苏东台人, 讲师, 博士。

引用该论文:

YANG Ji-nian,XU Ai-qin.Research Progress in Foaming and Molding Process of Polypropylene[J].Materials for mechancial engineering,2012,36(8):1～5
杨继年,许爱琴.聚丙烯发泡成型技术的研究进展[J].机械工程材料,2012,36(8):1～5

参考文献

【1】

KLEMNER D, FRISCH K C. Polymeric Foams[M].New York: Hanser Publishers, 1991.

【2】

刘培生.多孔材料引论[M].北京:清华大学出版社, 2004.

【3】

张旭锋, 王澜, 景森, 等.化学交联聚丙烯的性能及其发泡研究[J].中国塑料, 2005, 19(11):36-40.

【4】

NAGUIB H E, PARK C B. A study on the onset surface melt fracture of polypropylene materials with foaming additives[J].Journal of Applied Polymer Science, 2008, 109(6):3571-3577.

【5】

NAM G J, YOO J H, LEE J W. Effect of long-chain branches of polypropylene on rheological properties and foam-extrusion performances[J].Journal of Applied Polymer Science, 2005, 96(5):1793-1800.

【6】

杨淑静, 宋国君, 杨超.硅烷接枝交联法制备发泡用高熔体粘度聚丙烯[J].塑料工业, 2006, 34(增1):95-97.

【7】

信春玲, 洪粲, 何亚东.聚丙烯的流变性能及发泡性能研究[J].塑料, 2007, 36(1):51-55.

【8】

JAHANI Y, BARIKANI M. Rheological and mechanical study of polypropylene ternary blends for foam application[J].Iranian Polymer Journal, 2005, 14(4):361-370.

【9】

李立星, 张卫勤, 芦成, 等.聚丙烯挤出发泡材料的研究[J].现代塑料加工应用, 2008, 20(1):22-25.

【10】

王向东, 刘本刚, 陈士宏, 等.聚丙烯挤出发泡中的关键技术—加工设备和成型工艺研究[J].中国塑料, 2006, 20(4):20-24.

【11】

LEE P C, KAEWMESR W, WANG J, et al. Effect of die geometry on foaming behaviors of high-melt-strength polypropylene with CO2[J].Journal of Applied Polymer Science, 2008, 109(5):3122-3132.

【12】

ZEPEDA S C, GONZALEZ N R, RODRIGUE D. Effects of postextrusion conditions on the morphology of foamed high-density polyethylene/polypropylene blends[J].Journal of Applied Polymer Science, 2007, 106(2):1215-1227.

【13】

HWANG J J, ADACHI T, KUWABARA T, et al. Laminate model expressing mechanical properties of polypropylene foams having non-uniform cell-shape distributions[J].Materials Science and Engineering A, 2008, 487(1/2):369-376.

【14】

张纯, 罗筑, 于杰, 等.二次开模注射成型微孔发泡PP工艺及其性能研究[J].中国塑料, 2005, 19(8):67-70.

【15】

GUO M C, HEUZEY M C, CARREAU P J. Cell structure and dynamic properties of injection molded polypropylene foams[J].Polymer Engineering and Science, 2007, 47(7):1070-1081.

【16】

廖永灵, 何力, 李良, 等.温度对微孔发泡PP材料冲击性能的影响[J].塑料工业, 2007, 35(11):46-48.

【17】

何颖, 周丽, 龚维, 等.微孔发泡聚丙烯(PP)的性能的研究[J].现代机械, 2006, 24(3):67-68.

【18】

POP-ILIEV R, LIU F, LIU G B, et al. Rotational foam molding of polypropylene with control of melt strength[J].Advances in Polymer Technology, 2003, 22(4):280-296.

【19】

POP-ILIEV R. Processing of integral-skin cellular polymeric composites in rapid rotational foam molding[J].Acta Physica Polonica A, 2011, 120(2):292-297.

【20】

NAKAI S, TAKI K, TSUJIMURA I, et al. Numerical simulation of a polypropylene foam bead expansion process[J].Polymer Engineering and Science, 2008, 48(1):107-115.

【21】

ZHAI W T, KIM Y W, PARK C B. Steam-chest molding of expanded polypropylene foams-Part Ⅰ:DSC simulation of bead foam processing[J].Industrial & Engineering Chemistry Research, 2010, 49(20):9822-9829.

【22】

ZHAI W T, KIM Y W, JUNG D W, et al. Steam-chest molding of expanded polypropylene foams-Part Ⅱ: mechanism of interbead bonding[J].Industrial & Engineering Chemistry Research, 2011, 50(9):5523-5531.

【23】

BOUIX R, VIOT P, LATAILLADE J L. Polypropylene foam behaviour under dynamic loadings: strain rate, density and microstructure effects[J].International Journal of Impact Engineering, 2009, 36(2):329-342.

【24】

VIOT P. Hydrostatic compression on polypropylene foam[J].International Journal of Impact Engineering, 2009, 36(7):975-989.

【25】

李迎春, 谭能超, 韩朝昱, 等.发泡工艺对交联发泡PP板材性能的影响[J].工程塑料应用, 2003, 31(7):25-27.

【26】

LIU H, CHUAI C Z, IQBAL M, et al. Improving foam ability of polypropylene by crosslinking[J].Journal of Applied Polymer Science, 2011, 122:973-980.

【27】

张雯, 林剑英, 王月香, 等.一步法交联模压发泡聚丙烯的力学性能[J].高分子材料科学与工程, 2011, 27(6):118-121.

【28】

HAN D H, JANG J H, KIM H Y, et al. Manufacturing and foaming of high melt viscosity of polypropylene by using electron beam radiation technology[J].Polymer Engineering and Science, 2006, 46(4):431-437.

【29】

大卫伊夫斯. 泡沫塑料手册[M].周南桥, 彭响方, 谢小莉, 等译.北京:化学工业出版社, 2006.

【30】

ZHANG Z X, ZHANG S L, XIN Z X, et al. Polypropylene/waste ground rubber tire powder foams: a study of the relationship between processing and structure using supercritical carbon dioxide[J].E-Polymers, 2007, 132:1-12.

【31】

ANTUNES M, REALINHO V, VELASCO J I. Study of the influence of the pressure drop rate on the foaming behavior and dynamic-mechanical properties of CO2 dissolution microcellular polypropylene foams[J].Journal of Cellular Plastics, 2010, 46(6):551-571.

【32】

SPITAEL P, MACOSKO C W. Strain hardening in polypropylenes and its role in extrusion foaming[J].Polymer Engineering and Science, 2004, 44(11):2090-2100.

【33】

RACHTANAPUN P, SELKE S E M, MATUANA L M. Effect of the high-density polyethylene melt index on the microcellular foaming of high-density polyethylene/polypropylene blends[J].Journal of Applied Polymer Science, 2004, 93(1):364-371.

【34】

ZHAI W T, WANG H Y, YU J, et al. Foaming behavior of polypropylene/polystyrene blends enhanced by improved interfacial compatibility[J].Journal of Polymer Science, 2008, 46(16):1641-1651.

【35】

XIN C L, HE Y D, LI Q C, et al. Crystallization behavior and foaming properties of polypropylene containing ultra-high molecular weight polyethylene under supercritical carbondioxide[J].Journal of Applied Polymer Science, 2011, 119(3):1275-1286.

【36】

HUANG H X, XU H F. Preparation of microcellular polypropylene/polystyrene blend foams with tunable cell structure[J].Polymers for Advanced Technologies, 2011, 22(6):822-829.

【37】

KAEWMESRI W, RACHTANAPUN P, PUMCHUSAK J. Effect of solvent plasticization on polypropylene microcellular foaming process and foam characteristics[J].Journal of Applied Polymer Science, 2008, 107(1):63-70.

【38】

KIM S G, LEUNG S N, PARK C B, et al. The effect of dispersed elastomer particle size on heterogeneous nucleation of TPO with N2foaming[J].Chemical Engineering Science, 2011, 66(16):3675-3686.

【39】

ZHANG P, WANG X J, YANG Y, et al. Bubble growth in the microcellular foaming of CO2/polypropylene solutions[J].Journal of Applied Polymer Science, 2010, 118(4):1949-1955.