综述了B4C/TiB2复相陶瓷的烧结工艺, 以及原料粉体粒径和第三组元对复相陶瓷性能的研究进展。对比了热压烧结、放电等离子烧结和无压反应烧结B4C/TiB2复相陶瓷相对密度和力学性能的差别, 比较了三种烧结工艺的优缺点; 总结了多种金属单质、金属氧化物、碳、过渡金属碳化物等第三组元, 以及粉体粒径对复相陶瓷烧结工艺性等性能的影响规律; 展望了B
4C/TiB2复相陶瓷制备技术的发展趋势。
所属栏目
综 述上海市教委重点项目(13ZZ133); 上海工程技术大学研究生科研创新资助项目(15KY0506)
收稿日期
2015/10/202016/8/25
作者单位
吴 晓:上海工程技术大学材料工程学院, 上海 201620
杨亚云:上海工程技术大学材料工程学院, 上海 201620
林文松:上海工程技术大学材料工程学院, 上海 201620
备注
吴晓(1987-), 男, 浙江平湖人, 硕士研究生。
引用该论文:
WU Xiao,YANG Ya-yun,LIN Wen-song.Research Progress on B4C/TiB2 Composite Ceramics[J].Materials for mechancial engineering,2016,40(11):1~4
吴 晓,杨亚云,林文松.B4C/TiB2复相陶瓷材料的研究进展[J].机械工程材料,2016,40(11):1~4
参考文献
【1】
THEVENOT F. Boron carbides - a comprehensive review[J]. J Eur Ceram Soc, 1990, 6: 205-225.
【2】
ZORZI J E, PEROTTONI C A, JORNADA J A H. Hardness and wear resistance of B4C ceramics prepared with several additives[J]. Mater Lett, 2005, 59: 2932-2935.
【3】
JUNG J, KANG S. Advances in manufacturing boron carbide-aluminum composites[J]. J Am Ceram Soc, 2004, 87(1): 47-54.
【4】
DENG J. Microstructure and mechanical properties of hot pressed B4C/(W,Ti)C ceramic composites[J]. Ceram Int, 2002, 28: 425-430.
【5】
HEYDARI M S, BAHARVANDI H R. Comparing the effects of different sintering methods for ceramics on the physical and mechanical properties of B4C-TiB2 nanocomposites[J]. Int J Refrac Met & Hard Mater, 2015, 51: 224-232.
【6】
WANG Y, PENG H, YE F, et al. Effect of TiB2 content on microstructure and mechanical properties of in-situ fabricated TiB2/B4C composites[J]. Trans Nonferrous Metals Soc China, 2011, 21: 369-373.
【7】
MALEK O. Electrical discharge machining of B4C-TiB2 composites[J]. J Eur Ceram Soc, 2011, 31(11): 2023-2030.
【8】
唐军, 谭寿洪, 陈忠明, 等. B4C-TiB2复相陶瓷的强韧化研究[J]. 无机材料学报, 1997, 12(2): 169-174.
【9】
SKOROKHOD V V. High strength-high toughness B4C-TiB2 composites[J]. J Mater Sci Lett, 2000,19 (3): 237-239.
【10】
DELGADO Y P, STAIA M H, MALEK O, et al. Friction and wear response of pulsed electric current sintered TiB2-B4C ceramic composite[J]. Wear, 2014, 317(1/2): 104-110.
【11】
HUANG S G, VANMEENSEL K, MALEK O J A, et al. Microstructure and mechanical properties of pulsed electric current sintered B4C/TiB2 composites[J]. Mater Sci Eng A, 2011, 528(2): 1302-1309.
【12】
DUDINA D, HULBERT D, JIANG D, et al. In situ boron carbide-titanium diboride composites prepared by mechanical milling and subsequent spark prima sintering[J]. J Mater Sci, 2008, 43(10): 3569-3576.
【13】
HEYDARI M S, BAHARVANDI H R, DOLATKHAH K. Effect of TiO2 nanoparticles on the pressureless sintering of B4C-TiB2 nanocomposites[J]. Int J Refrac Met & Hard Mater, 2015, 51: 6-13.
【14】
SKOROKHOD V. Pressureless sintering of B4C-TiB2 ceramic composites[J]. Mater Sci Forum,1998, 282: 219-224.
【15】
喻亮, 茹红强, 蔡继东. 热压C-SiC-B4C-TiB2复合材料的组织与力学性能[J]. 中国有色金属学报, 2008,18(2): 271-277.
【16】
GOLDSTEIN A, YESHURUN Y, GOLDENBERG A. B4C/metal boride composites derived from B4C/metal oxide mixtures[J]. J Eur Ceram Soc, 2007, 27(2/3): 695-700.
【17】
LEVIN L, FRAGE N M P. A novel approach for the preparation of B4C-based cermets[J]. Int J Refract Met & Hard Mater, 2000, 18: 131-135.
【18】
YUE X, ZHAO S, LU P,et al. Synthesis and properties of hot pressed B4C-TiB2 ceramic composite[J]. Mater Sci Eng A, 2010,527(27/28): 7215-7219.
【19】
LU P, YUE X, YU L, et al. Effect of in situ synthesized TiB2 on the reaction between B4C and Al in a vacuum infiltrated B4C-TiB2-Al composite[J]. J Mater Sci, 2009, 44: 3483-3487.
【20】
MASHHADI M, TAHERI-NASSAJ E, MASHHADI M, et al. Pressureless sintering of B4C-TiB2 composites with Al additions[J]. Ceram Int, 2011, 37: 3229-3235.
【21】
DANIEL B S S, MURTHY V S R, MURTY G S. Metal-ceramic composites via in-situ methods[J]. Journal of Materials Processing Technology, 1997, 68(2): 132-155.
【22】
GUO F W, JIHONG Z, CHUNPING Z. Densification and mechanical properties of B4C based composites sintered by reaction hot-pressing[J]. Key Eng Mater, 2010, 434/435: 24-27.
【23】
SIGL L S, KLEEBE H J. Microcracking in B4C-TiB2 composites[J]. J Am Ceram Soc, 1995, 78: 2374-2380.
【24】
MCCUISTON R, LASALVIA J, MOSER B. Effect of carbon additions and B4C particle size on the microstructure and properties of B4C-TiB2 composites[M]// Mechanical Properties and Performance of Engineering Ceramics and Composites III.[s.l.]: [s.n.], 2007: 257-268.
【25】
HEYDARI M S, BAHARVANDI H R. Effect of different additives on the sintering ability and the properties of B4C-TiB2 composites[J]. Int J Refract Met & Hard Mater, 2015, 51: 61-69.
【26】
SIGL L S. Processing and mechanical properties of boron carbide sintered with TiC[J]. J Eur Ceram Soc, 1998, 18: 1521-1529.
【27】
LI D, ZHOU Y, GUO Y. Processing and characteristics of TiB2 toughened B-Ti-C composites[J]. Trans Nonferrous Metals Soc, 2003, 13: 314-320.